Aqua(η4-1,5-cyclooctadiene)[1 -(2-methoxyethoxymethyl)-3,5- dimethylpyrazole]rhodium(I) tetrafluoroborate

Anna Boixassa; Rene Mathieu; Noël Lugan; Josefina Pons; Josep Ros

doi:10.1107/S1600536803016155

Aqua(η⁴-1,5-cyclooctadiene)[1 -(2-methoxyethoxymethyl)-3,5- dimethylpyrazole]rhodium(I) tetrafluoroborate

Anna Boixassa, Rene Mathieu, Noël Lugan, Josefina Pons, Josep Ros

Departament de Química

Producció científica: Contribució a revista › Article › Recerca › Avaluat per experts

4 Cites (Scopus)

Resum

The title complex, [Rh(C8H12)(C9H 16N2O2)(H2O)](BF4) or [RhL(COD)(H2O)](BF4), is a monomer in the solid state. The RhI centre is in a square-planar arrangement. The four coordination sites are occupied by the N atom of the pyrazole ligand, the O atom from a water molecule and the centroids of the two cyclooctadiene olefin bonds. The structure is stabilized by hydrogen bonds between the coordinated water molecule and the two O atoms of the ether groups of the pyrazole ligand and one of the F atoms of the BF4 unit. © 2003 International Union of Crystallography Printed in Great Britain - all rights reserved.

Idioma original	Anglès
Revista	Acta Crystallographica Section E: Structure Reports Online
Volum	59
Número	8
DOIs	https://doi.org/10.1107/S1600536803016155
Estat de la publicació	Publicada - 1 d’ag. 2003

Accés al document

10.1107/S1600536803016155

Altres arxius i enllaços

https://www.scopus.com/pages/publications/15044350532

Com citar-ho

@article{c06903a559c9433bb4bbc0037e4fb6bc,

title = "Aqua(η4-1,5-cyclooctadiene)[1 -(2-methoxyethoxymethyl)-3,5- dimethylpyrazole]rhodium(I) tetrafluoroborate",

abstract = "The title complex, [Rh(C8H12)(C9H 16N2O2)(H2O)](BF4) or [RhL(COD)(H2O)](BF4), is a monomer in the solid state. The RhI centre is in a square-planar arrangement. The four coordination sites are occupied by the N atom of the pyrazole ligand, the O atom from a water molecule and the centroids of the two cyclooctadiene olefin bonds. The structure is stabilized by hydrogen bonds between the coordinated water molecule and the two O atoms of the ether groups of the pyrazole ligand and one of the F atoms of the BF4 unit. {\textcopyright} 2003 International Union of Crystallography Printed in Great Britain - all rights reserved.",

author = "Anna Boixassa and Rene Mathieu and No{\"e}l Lugan and Josefina Pons and Josep Ros",

year = "2003",

month = aug,

day = "1",

doi = "10.1107/S1600536803016155",

language = "English",

volume = "59",

number = "8",

}

TY - JOUR

T1 - Aqua(η4-1,5-cyclooctadiene)[1 -(2-methoxyethoxymethyl)-3,5- dimethylpyrazole]rhodium(I) tetrafluoroborate

AU - Boixassa, Anna

AU - Mathieu, Rene

AU - Lugan, Noël

AU - Pons, Josefina

AU - Ros, Josep

PY - 2003/8/1

Y1 - 2003/8/1

N2 - The title complex, [Rh(C8H12)(C9H 16N2O2)(H2O)](BF4) or [RhL(COD)(H2O)](BF4), is a monomer in the solid state. The RhI centre is in a square-planar arrangement. The four coordination sites are occupied by the N atom of the pyrazole ligand, the O atom from a water molecule and the centroids of the two cyclooctadiene olefin bonds. The structure is stabilized by hydrogen bonds between the coordinated water molecule and the two O atoms of the ether groups of the pyrazole ligand and one of the F atoms of the BF4 unit. © 2003 International Union of Crystallography Printed in Great Britain - all rights reserved.

AB - The title complex, [Rh(C8H12)(C9H 16N2O2)(H2O)](BF4) or [RhL(COD)(H2O)](BF4), is a monomer in the solid state. The RhI centre is in a square-planar arrangement. The four coordination sites are occupied by the N atom of the pyrazole ligand, the O atom from a water molecule and the centroids of the two cyclooctadiene olefin bonds. The structure is stabilized by hydrogen bonds between the coordinated water molecule and the two O atoms of the ether groups of the pyrazole ligand and one of the F atoms of the BF4 unit. © 2003 International Union of Crystallography Printed in Great Britain - all rights reserved.

UR - https://www.scopus.com/pages/publications/15044350532

U2 - 10.1107/S1600536803016155

DO - 10.1107/S1600536803016155

M3 - Article

SN - 1600-5368

VL - 59

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 8