An oscillating C<inf>2</inf><sup>2-</sup> unit inside a copper rectangle

Wing Yin Lo; Chi Ho Lam; Wendy Kit Mai Fung; Hong Zhe Sun; Vivian Wing Wah Yam; David Balcells; Feliu Maseras; Odile Eisenstein

doi:10.1039/b301842c

An oscillating C<inf>2</inf><sup>2-</sup> unit inside a copper rectangle

Wing Yin Lo, Chi Ho Lam, Wendy Kit Mai Fung, Hong Zhe Sun, Vivian Wing Wah Yam, David Balcells, Feliu Maseras, Odile Eisenstein

Departament de Química

Producció científica: Contribució a una revista › Article › Recerca › Avaluat per experts

20 Cites (Scopus)

Resum

[Cu4(μ-dppm)4(μ4-η1,η2-C≡C–)]2+ has been shown by 31P and 1H NMR studies to undergo two fluxional processes in solution, the oscillation of the C≡C2- unit inside the copper rectangle and the flipping of the diphosphines, and this has been supported by DFT(B3LYP) calculations. © 2003 The Royal Society of Chemistry.

Idioma original	English
Pàgines (de-a)	1260-1261
Revista	Chemical Communications
Volum	3
Número	11
DOIs	https://doi.org/10.1039/b301842c
Estat de la publicació	Publicada - 1 de gen. 2003

Accés al document

10.1039/b301842c

Com citar-ho

@article{05b38ab4aa48415ea011786f7bd7a31a,

title = "An oscillating C22- unit inside a copper rectangle",

abstract = "[Cu4(μ-dppm)4(μ4-η1,η2-C≡C–)]2+ has been shown by 31P and 1H NMR studies to undergo two fluxional processes in solution, the oscillation of the C≡C2- unit inside the copper rectangle and the flipping of the diphosphines, and this has been supported by DFT(B3LYP) calculations. {\textcopyright} 2003 The Royal Society of Chemistry.",

author = "Lo, {Wing Yin} and Lam, {Chi Ho} and Fung, {Wendy Kit Mai} and Sun, {Hong Zhe} and Yam, {Vivian Wing Wah} and David Balcells and Feliu Maseras and Odile Eisenstein",

year = "2003",

month = jan,

day = "1",

doi = "10.1039/b301842c",

language = "English",

volume = "3",

pages = "1260--1261",

number = "11",

}

TY - JOUR

T1 - An oscillating C22- unit inside a copper rectangle

AU - Lo, Wing Yin

AU - Lam, Chi Ho

AU - Fung, Wendy Kit Mai

AU - Sun, Hong Zhe

AU - Yam, Vivian Wing Wah

AU - Balcells, David

AU - Maseras, Feliu

AU - Eisenstein, Odile

PY - 2003/1/1

Y1 - 2003/1/1

N2 - [Cu4(μ-dppm)4(μ4-η1,η2-C≡C–)]2+ has been shown by 31P and 1H NMR studies to undergo two fluxional processes in solution, the oscillation of the C≡C2- unit inside the copper rectangle and the flipping of the diphosphines, and this has been supported by DFT(B3LYP) calculations. © 2003 The Royal Society of Chemistry.

AB - [Cu4(μ-dppm)4(μ4-η1,η2-C≡C–)]2+ has been shown by 31P and 1H NMR studies to undergo two fluxional processes in solution, the oscillation of the C≡C2- unit inside the copper rectangle and the flipping of the diphosphines, and this has been supported by DFT(B3LYP) calculations. © 2003 The Royal Society of Chemistry.

U2 - 10.1039/b301842c

DO - 10.1039/b301842c

M3 - Article

SN - 1359-7345

VL - 3

SP - 1260

EP - 1261

JO - Chemical Communications

JF - Chemical Communications

IS - 11

ER -

An oscillating C<inf>2</inf><sup>2-</sup> unit inside a copper rectangle

Resum

Accés al document

Fingerprint

Com citar-ho