TY - JOUR
T1 - Ammonia-free infiltration of NaBH4 into highly-ordered mesoporous silica and carbon matrices for hydrogen storage
AU - Peru, F.
AU - Garroni, S.
AU - Campesi, R.
AU - Milanese, C.
AU - Marini, A.
AU - Pellicer, E.
AU - Baró, M. D.
AU - Mulas, G.
PY - 2013/3/22
Y1 - 2013/3/22
N2 - In this work we focused on nanoconfinement of NaBH4 into highly-ordered Si-based mesoporous scaffold and its carbon replica by ammonia-free wet chemical impregnation. Structural and morphological characterization, performed by X-ray diffraction and transmission electron microscopy enabled us to confirm the effectiveness infiltration procedure. Desorption properties tested by temperature programmed desorption analyses highlighted a noticeable shift towards lower temperature compared to both bulk material and samples of similar systems referred to in the bibliographical data. © 2013 Elsevier B.V. All rights reserved.
AB - In this work we focused on nanoconfinement of NaBH4 into highly-ordered Si-based mesoporous scaffold and its carbon replica by ammonia-free wet chemical impregnation. Structural and morphological characterization, performed by X-ray diffraction and transmission electron microscopy enabled us to confirm the effectiveness infiltration procedure. Desorption properties tested by temperature programmed desorption analyses highlighted a noticeable shift towards lower temperature compared to both bulk material and samples of similar systems referred to in the bibliographical data. © 2013 Elsevier B.V. All rights reserved.
KW - Hydrogen absorbin materials
KW - Nanofabrications
KW - Nanostructured materials
KW - Sol-gel processes
KW - Transmission Electron Microscopy, TEM
KW - X-ray diffraction
UR - https://www.scopus.com/pages/publications/84886592066
U2 - 10.1016/j.jallcom.2013.02.141
DO - 10.1016/j.jallcom.2013.02.141
M3 - Article
SN - 0925-8388
VL - 580
JO - Journal of Alloys and Compounds
JF - Journal of Alloys and Compounds
ER -