TY - JOUR
T1 - {Ag5[μ2-S-(CH2)3-NHMe 2]3[μ2-S-(CH2) 3-NMe2]3}2+, the first thiolate complex of a metal with trigonal bipyramido-M5-trigonal prismo-S 6 polyhedral stereochemistry
AU - González-Duarte, Pilar
AU - Sola, Joan
AU - Vives, Josep
AU - Solans, Xavier
PY - 1987/12/1
Y1 - 1987/12/1
N2 - The synthesis and structure of {Ag5[μ2-S-(CH 2)3-NHMe2]3[μ2-S- (CH2)3-NMe2]3}(ClO4) 2; the Ag5S6 core of the cage cation provides the only known case of an [Mx(SR)y] aggregate that can be described as a trigonal bipyramid of metal atoms enclosed within a regular trigonal prism of doubly bridging thiolate ligands.
AB - The synthesis and structure of {Ag5[μ2-S-(CH 2)3-NHMe2]3[μ2-S- (CH2)3-NMe2]3}(ClO4) 2; the Ag5S6 core of the cage cation provides the only known case of an [Mx(SR)y] aggregate that can be described as a trigonal bipyramid of metal atoms enclosed within a regular trigonal prism of doubly bridging thiolate ligands.
U2 - 10.1039/C39870001641
DO - 10.1039/C39870001641
M3 - Article
SN - 0022-4936
SP - 1641
EP - 1642
JO - Journal of the Chemical Society D: Chemical Communications
JF - Journal of the Chemical Society D: Chemical Communications
IS - 21
ER -