TY - JOUR
T1 - A transition metal complex as a ligand in the chemistry of group (IV) elements
AU - Siddiqi, K. S.
AU - Aqra, Fathi M.A.M.
AU - Shah, S. A.
AU - Zaidi, S. A.A.
AU - Casabo, J.
AU - Teixidor, F.
PY - 1993/1/1
Y1 - 1993/1/1
N2 - Heterobimetallic complexes of the type [Cu(TETA)Cl2MCl2] (M = Si, Ge, Sn, Ti and Zr; TETA = tiethylene tetramine) have been synthesized and characterized by elemental analyses, ESR, electronic and IR spectra and conductivity measurements. The complex [Cu(TETA)Cl2SnPh2] has also been prepared. The results indicate that [Cu(TETA)]Cl2 is square planar and ionic in nature, while its bimetallic complexes, [Cu(TETA)Cl2MCl2] and [Cu(TETA)Cl2SnPh2], are covalent with an octahedral environment around the copper(II) ion. © 1993.
AB - Heterobimetallic complexes of the type [Cu(TETA)Cl2MCl2] (M = Si, Ge, Sn, Ti and Zr; TETA = tiethylene tetramine) have been synthesized and characterized by elemental analyses, ESR, electronic and IR spectra and conductivity measurements. The complex [Cu(TETA)Cl2SnPh2] has also been prepared. The results indicate that [Cu(TETA)]Cl2 is square planar and ionic in nature, while its bimetallic complexes, [Cu(TETA)Cl2MCl2] and [Cu(TETA)Cl2SnPh2], are covalent with an octahedral environment around the copper(II) ion. © 1993.
U2 - 10.1016/S0277-5387(00)81552-1
DO - 10.1016/S0277-5387(00)81552-1
M3 - Article
SN - 0277-5387
VL - 12
SP - 949
EP - 953
JO - Polyhedron
JF - Polyhedron
IS - 8
ER -