TY - JOUR
T1 - A novel Rh-B σ bond. Crystal structure of [N(CH3) 4][RhCl{7,8-μ-S(CH2CH2)S-C2B 9H10}{σ-7,8-μ-S(CH2CH 2)S-C2B9H9}]
AU - Teixidor, Francesc
AU - Romerosa, Antonio
AU - Viñas, Clara
AU - Rius, Jordi
AU - Miravittles, Carles
AU - Casabó, Jaume
PY - 1991/12/1
Y1 - 1991/12/1
N2 - The complex [N(CH3)4][RhCl{7,8-μ-S(CH 2CH2)S-C2B9H10} {σ-7,8-μ-S(CH2CH2)S-C2B 9H9}] is an octahedral Rh(III) complex; the sixth coordination site is occupied by a σ-bond B-Rh in this first example of B(3)-Rh coordination.
AB - The complex [N(CH3)4][RhCl{7,8-μ-S(CH 2CH2)S-C2B9H10} {σ-7,8-μ-S(CH2CH2)S-C2B 9H9}] is an octahedral Rh(III) complex; the sixth coordination site is occupied by a σ-bond B-Rh in this first example of B(3)-Rh coordination.
UR - https://www.scopus.com/pages/publications/37049070108
U2 - 10.1039/C39910000192
DO - 10.1039/C39910000192
M3 - Article
SN - 0022-4936
SP - 192
EP - 193
JO - Journal of the Chemical Society D: Chemical Communications
JF - Journal of the Chemical Society D: Chemical Communications
IS - 3
ER -