A base-stabilized sila-β-lactone and a donor/acceptor-stabilized silanoic acid

Ricardo Rodriguez; David Gau; Thibault Troadec; Nathalie Saffon-Merceron; Vicenç Branchadell; Antoine Baceiredo; Tsuyoshi Kato

doi:10.1002/anie.201304482

A base-stabilized sila-β-lactone and a donor/acceptor-stabilized silanoic acid

Ricardo Rodriguez, David Gau, Thibault Troadec, Nathalie Saffon-Merceron, Vicenç Branchadell, Antoine Baceiredo, Tsuyoshi Kato

Departament de Química

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Resum

A stable base-stabilized sila-β-lactone was successfully synthesized and fully characterized. Interestingly, this sila-β-lactone shows a very unique reactivity toward ethanol, leading to the formation of an isolable donor/acceptor-stabilized silanoic acid. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Idioma original	Anglès
Pàgines (de-a)	8980-8983
Revista	Angewandte Chemie - International Edition
Volum	52
Número	34
DOIs	https://doi.org/10.1002/anie.201304482
Estat de la publicació	Publicada - 19 d’ag. 2013

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10.1002/anie.201304482

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title = "A base-stabilized sila-β-lactone and a donor/acceptor-stabilized silanoic acid",

abstract = "A stable base-stabilized sila-β-lactone was successfully synthesized and fully characterized. Interestingly, this sila-β-lactone shows a very unique reactivity toward ethanol, leading to the formation of an isolable donor/acceptor-stabilized silanoic acid. Copyright {\textcopyright} 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.",

keywords = "phosphorus, silanoic acid, silanones, silicon, silylene",

author = "Ricardo Rodriguez and David Gau and Thibault Troadec and Nathalie Saffon-Merceron and Vicen{\c c} Branchadell and Antoine Baceiredo and Tsuyoshi Kato",

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T1 - A base-stabilized sila-β-lactone and a donor/acceptor-stabilized silanoic acid

AU - Rodriguez, Ricardo

AU - Gau, David

AU - Troadec, Thibault

AU - Saffon-Merceron, Nathalie

AU - Branchadell, Vicenç

AU - Baceiredo, Antoine

AU - Kato, Tsuyoshi

PY - 2013/8/19

Y1 - 2013/8/19

N2 - A stable base-stabilized sila-β-lactone was successfully synthesized and fully characterized. Interestingly, this sila-β-lactone shows a very unique reactivity toward ethanol, leading to the formation of an isolable donor/acceptor-stabilized silanoic acid. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

AB - A stable base-stabilized sila-β-lactone was successfully synthesized and fully characterized. Interestingly, this sila-β-lactone shows a very unique reactivity toward ethanol, leading to the formation of an isolable donor/acceptor-stabilized silanoic acid. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

KW - phosphorus

KW - silanoic acid

KW - silanones

KW - silicon

KW - silylene

U2 - 10.1002/anie.201304482

DO - 10.1002/anie.201304482

M3 - Article

SN - 1433-7851

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

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ER -

A base-stabilized sila-β-lactone and a donor/acceptor-stabilized silanoic acid

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