TY - JOUR
T1 - 15-Membered triolefinic macrocycles, their coordination chemistry with transition metals, and the catalytic properties of their palladium metal complexes. A review
AU - Moreno-Mañas, Marcial
AU - Pleixats, Roser
AU - Roglans, Anna
AU - Sebastián, Rosa M.
AU - Vallribera, Adelina
PY - 2004/1/1
Y1 - 2004/1/1
N2 - (E,E,E)-1,6,11-Tris(arenesulfonyl)-1,6,11-triazacyclopentadeca-3,8, 11-trienes, 1, are prepared from arenesulfonamides and trans-1,4-dibromo-2-butene. Macrocycles 1 coordinate palladium(0), platinum(0), and silver(I), and the palladium complexes are useful and reutilizable catalysts or precatalysts in Suzuki cross-couplings, butadiene telomerizations, hydroarylation of alkynes, and in the Heck reaction. Structurally related macrocycles are also available by similar synthetic procedures.
AB - (E,E,E)-1,6,11-Tris(arenesulfonyl)-1,6,11-triazacyclopentadeca-3,8, 11-trienes, 1, are prepared from arenesulfonamides and trans-1,4-dibromo-2-butene. Macrocycles 1 coordinate palladium(0), platinum(0), and silver(I), and the palladium complexes are useful and reutilizable catalysts or precatalysts in Suzuki cross-couplings, butadiene telomerizations, hydroarylation of alkynes, and in the Heck reaction. Structurally related macrocycles are also available by similar synthetic procedures.
KW - Alkene ligands
KW - Catalysis
KW - Heterocycles
KW - Macrocycles
KW - Olefin complexes
U2 - 10.3998/ark.5550190.0005.414
DO - 10.3998/ark.5550190.0005.414
M3 - Review article
SN - 1424-6376
VL - 2004
SP - 109
EP - 129
JO - Arkivoc
JF - Arkivoc
IS - 4
ER -