TY - JOUR
T1 - α,α′-Bis(trifluoromethyl)-9,10-anthracenedimethanol: Enantioselective synthesis and bidentate complexes with benzenedimethanols
AU - Estivill, Carla
AU - Ivanov, Petko M.
AU - Pomares, Marta
AU - Sánchez-Arís, Marta
AU - Virgili, Albert
PY - 2004/5/10
Y1 - 2004/5/10
N2 - α,α′-Bis(trifluoromethyl)-9, 10-anthracenedimethanol was prepared by a one pot stereoselective double reduction in good yield and excellent enantiomeric excess. We examined the association with ortho- and meta-benzenedimethanol showing bidentate complexes stable enough to be studied by low temperature NMR. Molecular modeling helped us to propose an association complex. © 2004 Elsevier Ltd. All rights reserved.
AB - α,α′-Bis(trifluoromethyl)-9, 10-anthracenedimethanol was prepared by a one pot stereoselective double reduction in good yield and excellent enantiomeric excess. We examined the association with ortho- and meta-benzenedimethanol showing bidentate complexes stable enough to be studied by low temperature NMR. Molecular modeling helped us to propose an association complex. © 2004 Elsevier Ltd. All rights reserved.
U2 - 10.1016/j.tetasy.2004.03.019
DO - 10.1016/j.tetasy.2004.03.019
M3 - Article
SN - 0957-4166
VL - 15
SP - 1431
EP - 1436
JO - Tetrahedron Asymmetry
JF - Tetrahedron Asymmetry
IS - 9
ER -